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Azide Coordination to Polyoxometalates: Synthesis of (Bu4N)4.3K0.7[PW11O39FeIIIN3]⋅2.5H2O

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Abstract

A new iron polyoxometalate complex, (Bu4N)4.3K0.7[PW11O39FeIIIN3]⋅2.5H2O (1), has been synthesized in 50% yield by the reaction of K7[PW11O39]⋅14H2O, Fe(NO3)3 ⋅ 9H2O, and NaN3 with subsequent addition of Bu4NBr. The compound has been characterized by elemental analysis, mass spectrometry, and vibrational spectroscopy. The unit cell parameters of 1 have been determined by single-crystal X-ray diffraction: cubic crystal system, space group I\(\bar {1}\)3m, a = 17.82(1) Å, which is typical of salts of Keggin anions with strongly disordered Bu4N+ cations.

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ACKNOWLEDGMENTS

The authors are grateful to A.V. Anyushin for help in carrying out the experiments, C. Vicente (Jaime I University Center for Collective Use) for obtaining mass spectrometric data, and A.L. Gushchin for conducting the electrochemical study, as well as the Shared Facility Center of the Institute of Inorganic Chemistry, SB RAS, for performing single crystal X-ray diffraction and DTA.

Funding

The work was supported by the Ministry of Science and higher Education of the Russian Federation, project no. 121031700313-8.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    V. S. Korenev, P. A. Abramov & M. N. Sokolov

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  1. V. S. Korenev
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  2. P. A. Abramov
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  3. M. N. Sokolov
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Correspondence to V. S. Korenev.

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Translated by G. Kirakosyan

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Korenev, V.S., Abramov, P.A. & Sokolov, M.N. Azide Coordination to Polyoxometalates: Synthesis of (Bu4N)4.3K0.7[PW11O39FeIIIN3]⋅2.5H2O. Russ. J. Inorg. Chem. 67, 1763–1768 (2022). https://doi.org/10.1134/S0036023622600897

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