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STUDY OF THE STRUCTURE OF Ag(I) SOLVATE COMPLEXES BY MEANS OF POLYOXOMETALATES: CRYSTALLIZATION FROM THE AgNO3/(Bu4N)4[β-Mo8O26]/DMF SYSTEM. REVIEW

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Abstract

The review summarizes information about the known Ag+ solvate complexes isolated and structurally characterized as adducts and/or salts with polyoxometalates. The AgNO3/(Bu4N)4[β-Mo8O26]/N,N-dimethylformamide (DMF) system along with the complexes isolated for the first time are considered in detail: (Bu4N)4[Ag2(NO3)2Mo8O26]; (Bu4N)2n[Ag1.8(MoO2)0.2Mo8O26]n; (Bu4N)4[Ag2(DMF)4Mo8O26] [Ag2(DMF)2Mo8O26]; (Bu4N)4[Ag2(DMF)4Mo8O26][Ag2(DMF)2Mo8O26]·0.25DMF.

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The work was supported by the grant of the President of the Russian Federation (No. MD-396.2021.1.3).

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  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Abramov

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Russian Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 12, 103726.https://doi.org/10.26902/JSC_id103726

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Abramov, P.A. STUDY OF THE STRUCTURE OF Ag(I) SOLVATE COMPLEXES BY MEANS OF POLYOXOMETALATES: CRYSTALLIZATION FROM THE AgNO3/(Bu4N)4[β-Mo8O26]/DMF SYSTEM. REVIEW. J Struct Chem 63, 2068–2082 (2022). https://doi.org/10.1134/S0022476622120186

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